| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Dr. Salim A. Salim | Ambassador | 1964 - 1965 |
| 2 | H.E. Ahmed H. Diria | Ambassador | 1965 - 1968 |
| 3 | H.E. George M. Nhigula | Ambassador | 1969 - 1971 |
| 4 | H.E. Sebastian Chale | Ambassador | 1971 - 1972 |
| 5 | H.E. Christopher P. Ngaiza | Ambassador | 1973 - 1976 |
| 6 | H.E. Ali H. Mwinyi | Ambassador | 1977 - 1981 |
| 7 | H.E. Abdallah B. Suedi | Ambassador | 1981 - 1985 |
| 8 | H.E. Mohamad A. Foum | Ambassador | 1986 - 1993 |
| 9 | H.E. Muhammed M. H. Mzale | Ambassador | 1993 - 2002 |
| 10 | H.E. Kassim M. J. Mwawado | Ambassador | 2002 - 2007 |
| 11 | H.E. Ali Shauri Haji | Ambassador | 2007 - 2012 |
| 12 | H.E. Muhamed Haji Hamza | Ambassador | 2012 - 2017 |
| 13 | H.E. Major Gen. Issa Suleiman Nassor | Ambassador | 2017 - 2019 |
| 14 | H.E. Major Gen. Anselm S. Bahati | Ambassador | 2019 - 2022 |
| 15 | Dr. Emmanuel John Nchimbi | Ambassador | 2022 - 2023 |
